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81.
Aihuan Dun Jingsong Wei Fuxi Gan 《Applied Physics A: Materials Science & Processing》2011,103(1):139-147
Thermocapillary and chemicapillary effects are known to coexist in a material molten pool when irradiated by a pulse laser.
According to the effects, we fabricate various patterns with different shapes on a Sb2Te3 phase change thin film by precisely adjusting the pulse energy. In this process, the laser power is fixed at 5.0 mW, and
the pulse width is adjusted from 100 ns to 5 ns. The shape of the patterns gradually changes from a dimple-bowl shape, a dome
shape, a “Sombrero” shape to a deep-bowl shape following an increase in the pulse energy, which corresponds to the crystallization-threshold,
bump-threshold, rupture-threshold, and ablation-threshold of the material. The different patterns are the results of the competition
between the thermocapillary and chemicapillary effects in the molten pool, which determine the nature of the flow and lead
to the different patterns in different laser parameters. 相似文献
82.
The optical characteristics of transparent lead magnesium niobate titanate (PMNT) electro-optic ceramic, including the electro-optic phase modulation, electric hysteresis property and thermo-optic coefficient, are investigated in detail. Based on this novel ceramic, a polarization independent electro-optic switch by using fiber Sagnac interferometer (FSI) structure is realized. An initial π-shift is introduced into the Sagnac loop to eliminate the effect of the polarization orientation of the incident light on the switch performance. Then an electrically controllable PMNT phase retarder is used to switch the optical signal between the reflection and transmission ports. Some theoretical analyses are given and the switch performances are also discussed, including the thermal characteristic and different switching frequency response. 相似文献
83.
84.
Jijing XuGuijuan Ji Haifeng ZouYanhua Song Shucai Gan 《Journal of magnetism and magnetic materials》2011,323(1):156-161
Sm-substituted barium hexaferrites, Ba3−xSmxCo2Fe24O41 (x=0-0.25), were prepared by a conventional ceramic sintering method. The microstructure, complex permittivity, complex permeability and static magnetic properties of the samples were studied using powder X-ray diffraction, field emission scanning electron microscopy, vector network analyzer and vibrating sample magnetometry. The results reveal that by introducing a relatively small amount of Sm3+ instead of Ba2+ an important modification of both structure and high-frequency electromagnetic properties can be obtained. Doping of Sm3+ suppressed the grain growth and gave rise to a decrease of the grain size. As the Sm content increases, the static magnetic properties continuously increase. The real part and imaginary part of complex permittivity initially increase with Sm content, and then decreases when x>0.10. The imaginary part of complex permeability decreases after Sm3+ is doped. There is no obvious change in the real part of the complex permeability for different Sm contents. The reasons are discussed using electromagnetic theory. 相似文献
85.
Qitu Hu Zibao Gan Xiuwen Zheng Qingfu Lin Baofeng Xu Aihua Zhao Xu Zhang 《Superlattices and Microstructures》2011
Hybrid nanostructures composed of gold nanoparticles (NPs) and carbon nanotubes (CNTs) have been prepared by a microwave-assisted method in the mixed solvents of oleylamine and oleic. The morphology, structure and composition of as-obtained Au/CNT composites are characterized by transmission electron microscopy (TEM), energy dispersive X-ray spectroscopy (EDS), X-ray diffraction (XRD). The composites show characteristic plasmon absorption of Au NPs in the Ultraviolet–visual spectrum. Fourier transform infrared spectrum shows the successful introduction of functional groups on the surface of CNTs, which are crucial factors to assist the nucleation in situ of Au NPs on the surface of CNTs. Electrochemical measurements show the enhancement electrochemical response for the gold electrode modified with Au/CNT composites. 相似文献
86.
目前,将天然高分子蛋白和聚合物共混利用静电纺丝法制作各种组织工程支架材料倍受关注。基于这种研究背景,在本文中利用静电纺丝技术,制备了丝素(SF)/胶原(COL)/聚左旋乳酸(PLLA)和SF/COL/聚左旋乳酸-己内酯(PLCL)两种共混复合纤维膜,通过扫描电镜(SEM)对纤维形态结构分析,发现复合纤维形貌良好,直径较为均一。同时改变纺丝液中高分子蛋白的比例,复合纤维的直径也随之减小。此外,对复合纤维进行了力学性能测试,发现随着聚合物含量的增加,复合纤维膜的力学性能得以改善,SF/COL/PLCL组复合纤维的拉伸性能明显优于SF/COL/PLLA组。 相似文献
87.
A spectral similarity measure was developed that can differentiate subtle differences between two spectra. The spectra are digitalized into a vector. The difference between the two spectra is defined by a difference vector, which is one spectrum minus the other. The spectral similarity measure is transformed into a hypothesis test of the similarities and differences between the two spectra. The scalar mean of the difference vector is used as the statistical variable for the hypothesis test. A threshold for the hypothesis that the spectra are different was proposed. The Bayesian prior odds ratio was estimated from multiple spectra of the same sample. The posterior odds ratio was used to quantity the spectral similarity measure of the two spectra. Diffuse reflectance near-infrared spectra of tobacco samples of two formulations were used to demonstrate this method. The results show that this new method can detect subtle differences between the spectra. 相似文献
88.
Chang-Zhu Yu You-Zhao He Hai-Yang Xie Yong Gao Wu-Er Gan Jun Li 《Journal of chromatography. A》2009,1216(20):4504-4509
A wall-free detection method based on liquid junction in a capillary gap was proposed for laser-induced fluorescence (LIF) of capillary electrophoresis (CE). The capillary gap of the wall-free cell was fabricated by etching a 10-mm × 50-μm I.D. fused-silica capillary to obtain a polyimide coating sleeve, decoating about 6 mm at one end of both 50 μm I.D. separation and liquid junction capillary, inserting the treated capillary ends into the coating sleeve oppositely, fixing the capillaries with a gap distance of 140 μm by epoxy glue and removing the coating sleeve by burning. The theoretical model, experimental results and wall-free cell images indicated that the gap distance and applied voltage were main influence factors on the wall-free detection. Since the wall-free cell increased the absorption light path and avoided the stray light from the capillary wall, it improved the ratio of signal to noise and limit of detection (LOD) of CE-LIF. Three flavin compounds of riboflavin (RF), flavin mononucleotide sodium (FMN) and flavin adenine dinucleotide disodium (FAD) were used to evaluate the wall-free detection method. Compared with on-column cell, the LODs of the wall-free cell were improved 15-, 6- and 9-fold for RF, FMN and FAD, respectively. The linear calibration concentrations of the flavins ranged from 0.005 to 5.0 μmol/L. The column efficiency was in the range from 1.0 × 105 to 2.5 × 105 plates. The wall-free detection of CE-LIF was applied to the analysis of the flavins in spinach and lettuce leaves. 相似文献
89.
Hai-Yang Xie You-Zhao HeWu-Er Gan Guo-Ni FuLian Li Fang HanYong Gao 《Journal of chromatography. A》2009,1216(15):3353-3359
A simple and efficient dual preconcentration method of on-column liquid–liquid–liquid microextraction (LLLME) coupled with base stacking was developed for capillary zone electrophoresis (CZE) in this paper. Four N-methyl carbamates were used as target compounds to evaluate the enrichment means. The carbamates in sample solutions (donor phase) were extracted into a dodecanol phase immobilized on a porous hollow fiber, hydrolyzed and back extracted into 0.20 μL running buffer (acceptor phase) of 30 mmol/L methylamine hydrochloride (pH 11.6) containing 0.5 mmol/L tetradecyltrimethylammonium bromide inside the hollow fiber, stacked further with 0.5 mol/L NaOH injected at −10 kV for 60 s, and separated by CZE. Analytical parameters affecting the LLLME, base stacking and CZE were investigated, including sample solution volume, pH and temperature, extraction time, stirring rate, buffer component, buffer pH, NaOH concentration, stacking time, etc. The enrichment factors of the carbamates were higher than 1100. The relative standard deviation (RSD) of peak height and limits of detection (LODs) were 4.5–5.5% (n = 6) and 2–4 ng/mL (S/N = 3) for standard solutions, respectively. The proposed method was applied to the analysis of vegetable and fruit samples with the RSD less than 6.0% (n = 3) and LODs of 6–10 ng/g (S/N = 3). The calibration solutions were prepared by diluting the stock solutions with blank sample solutions, and the calibration concentrations ranged from 0.012 to 1.0 μg/mL (r > 0.9951). The analytical results demonstrated that the LLLME coupled with base stacking was a simple, convenient and reliable on-column sample pretreatment method for the analysis of anionic analytes in CZE. 相似文献
90.
Yuhong Wang Yunting Gan Roger Whiting Guanzhong Lu 《Journal of solid state chemistry》2009,182(9):2530-2534
A new method has been developed for the preparation of sulfated titania (S-TiO2) supported on mesoporous silica. The use of direct exchange of metal containing precursors for the surfactants in the as-synthesized MCM-41 substrate produced a product with high sulfur content without serious blockage of the pore structure of MCM-41. The pore sizes and volumes of the resultant S-TiO2/MCM-41 composites were found to vary markedly with the loading of TiO2. The strong acidic character of the composites obtained was examined by using them as catalysts for the esterification of acetic acid and n-butanol. 相似文献